适用于快速远程检测海水中氰化物的方法研究     

姚竞芳  袁涛  敖俊杰  顾佳媛  李佳凡 《海洋科学》2018,42(11):24-28

建立了一种适用于海洋远程快速检测氰化物的检测方法,设计了一体化检测装置,未来可搭载到无人艇上实现自动快速检测。针对最佳检测条件进行了一系列优化,得到最佳检测条件:对于100 mL的待测样品,加入酒石酸固体1.5 g;用1～2滴浓度为150 g/L的碳酸钠溶液浸润苦味酸试纸;加热温度80℃,加热时间10min。在最佳检测条件下,检测检出限达0.3mg/L。该方法实现了适用于海水氰化钠的远程检测,大大提高了检测效率,无需人员进入污染现场,安全性高。可广泛用于海洋危化品泄漏、湖泊污染、现场应急筛选等场合的水体样品快速检测。  相似文献   

脚靴式海上升压站灌浆连接段强度分析研究   总被引：1，自引：1，他引：0  

王永发  孙震洲  汤群益  陈杰峰 《海洋工程》2020,38(5):107-115

与国内已建成的海上升压站相比，脚靴式海上升压站导管架对桩和套筒间的灌浆连接强度要求更高，完全套用单桩风电结构的分析方法会使结构设计不准确。由于桩和套筒之间设置有剪力键，当特殊情况时还需增加灌浆连接增强钢筋，在地震及撞船作用下容易导致灌浆接触界面分离等破坏，当前尚未有针对此类情况系统的灌浆连接强度校核方法。以某脚靴式海上升压站为例，分析其在在位、撞船、地震、疲劳等多个主控工况下灌浆连接、剪力键及增强钢筋的强度及稳定性，结果表明该海上升压站灌浆连接段满足设计要求，并研究了各参数对灌浆连接段强度的敏感程度，为今后脚靴式海上升压站各主控工况下的灌浆连接段强度分析、优化设计提供参考与借鉴。  相似文献   

北部湾地区海砂填料的动力特性分析     

王家全  陈胜前  唐毅  黄世斌  黄钦政 《海洋工程》2020,38(5):149-155

为研究北部湾地区海砂填料的动力特性，采用高级动态三轴测试系统开展循环荷载下的动三轴试验，研究不同围压及不同动应力幅值对海砂动力特性的影响规律。试验结果表明：轴向累计应变随围压增加而减小，围压150 kPa时振次10 000后应变仅为3%；随着动应力幅值的增大轴向累积应变随之增大，且达到破坏标准的时间越短。动弹性模量随着动应力幅值和围压的增加而增大，不同围压下动弹性模量随动应变的增加出现先骤减再略减后稳定的发展趋势，ε_d>0.3%后开始趋于稳定；不同动应力幅值下动弹性模量出现先增后减直至稳定的趋势，其中动应力幅值对动弹性模量有明显的影响，围压影响相对较小。孔压比随动应力幅值增加而减小，随围压增加而增加。  相似文献   

废弃泥浆底部真空−上部堆载预压模型试验研究     

詹良通  张斌  郭晓刚  江文豪 《岩土力学》2020,41(10):3245-3254

针对工程泥浆回填废弃矿坑处置的安全问题，开展底部真空和上部堆载预压处理废弃工程泥浆的模型试验，探讨该技术在废弃矿坑回填处置工程应用的可行性。试验结果表明，底部真空和上部堆载预压使得泥浆含水率显著降低及泥土的强度明显提高，处理一个月后，含水率从初始450%降低至95%～105%，体积减量达到73.4%；不排水强度由初始为0的状态提高至9.8～13.4 kPa。在初始的静置阶段，泥浆颗粒沉积存在重力分异现象，粗颗粒在底部沉积有助于缓解真空预压过程中淤堵问题。底部真空作用下，泥浆中孔隙水渗流方向并非完全一维向下，在径向存在水力梯度。处理后泥土压缩性与软土相近，渗透性优于软土。基于试验结果和大应变固结理论，考虑泥浆的自重固结以及压缩性与渗透性的非线性变化，利用有限差分法分析了单次回填厚度对泥浆层固结时间和减量效果的影响，提出了现场实施的工艺参数建议。  相似文献   

冻融循环下花岗岩剪切蠕变试验与模型研究     

张峰瑞  姜谙男  杨秀荣  申发义 《岩土力学》2020,41(2):509-519

为探讨冻融对寒区工程岩石剪切蠕变特性的影响，以吉林省辉白隧道花岗岩为研究对象，对经历不同冻融循环次数的试样开展细观特征分析和剪切蠕变试验。试验结果表明：（1）随着冻融次数的增加，试样裂隙、孔隙不断扩展，岩石表面损伤现象愈发明显；（2）试样主要以中小孔隙为主，孔隙度随着冻融次数的增加呈非线性增长趋势；（3）随着冻融循环次数增加，蠕变变形量和蠕变速率逐渐增大，而蠕变时长、破坏应力和长期强度均呈现明显降低趋势。根据试验结果，进行冻融岩石非定常蠕变参数的表达，提出了冻融岩石损伤黏性元件，构建了花岗岩冻融剪切蠕变本构模型。将蠕变试验曲线和理论模型拟合曲线进行对比，验证了模型的正确性和适用性。通过对蠕变参数进行敏感性分析，研究了其对花岗岩蠕变变形的影响，并给出了蠕变参数随冻融循环次数的变化规律。该研究结果对于寒区岩体工程长期稳定性评价具有指导意义。  相似文献   

GBW10010a大米标准物质复(研)制及数据特征     

杨榕  顾铁新  潘含江  刘妹  周国华 《岩矿测试》2020,39(6):866-877

随着我国对生态文明建设的重视，自然资源综合调查势在必行，对生物标准物质亦提出了新的需求。当前相关调研工作已经大面积开展，自然资源综合调查、农产品与食品安全评价都需要对生物样品元素组成进行准确测试，需要以生物标准物质作为生物成分测试量值比对和溯源的基础，因此对生物基体标准物质的需求量大幅增加。大米作为主要粮食之一，其食品安全日益受到重视，对大米中的化学成分进行准确的分析测试具有重要的现实意义，因而对大米标准物质的需求量尤为突出，但目前大米成分分析标准物质已供不应求。本文严格按照《标准物质定值的通用原则及统计学原理》（JJF 1343—2012）和《地质分析标准物质的研制》（JJF 1646—2017）等相关规范要求，开展了GBW10010a大米成分分析标准物质的复（研）制工作，包括样品采集、加工制备、均匀性检验、稳定性检验、多家实验室协作定值测试及不确定度评定等关键环节。结果表明：本次复（研）制的大米标准物质定值成分多样、量值准确可靠，符合国家一级标准物质的要求。GBW10010a共定值54项主微量元素，包括Ag、Al、As、B、Ba、Be、Bi、Ca、Cd、Ce、Co、Cr、Cs、Cu、Dy、Er、Eu、Fe、Gd、Ge、Hg、Ho、K、La、Li、Ho、Mg、Mn、Mo、N、Na、Nb、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Sc、Se、Si、Sm、Sr、Tb、Th、Tl、Tm、U、V、Y、Yb、Zn，其中的39项元素给出了标准值及不确定度，包括Ag、Al、As、B、Ba、Ca、Cd、Ce、Co、Cs、Cu、Dy、Er、Fe、Hg、K、Li、Mg、Mn、Mo、N、Na、Nd、Ni、P、Pb、Pr、Rb、S、Sb、Se、Si、Sm、Sr、Tb、Tl、Y、Yb、Zn；15项元素提供参考值，包括Be、Bi、Cr、Eu、Gd、Ge、Ho、Ho、La、Nb、Sc、Th、Tm、U、V。与原有GBW10010大米标准物质相比较，GBW10010a中As、Cd、Co、Cr、Cu、Hg、Mn、Mo、Ni、Zn等重金属元素含量显著下降，其中Cd、Cu、Zn降幅较大，分别下降约39%、43%、38.7%，一定程度上反映了农田生态环境的改善。本批标准物质定值元素总数量增加了6项，新增定值元素Ag、Nb（Nb给出参考值），并且各项元素不确定度范围整体上有所缩小，如Al、Cd、Cu、Fe、K、Mg、Mo、Na、P、Pb、Se、Zn等对生物易有影响的重要元素，表明了地质分析测试方法技术的进步及定值水平的提高。本批标准物质定值元素涵盖了具有生物效应的大部分主微量元素，适用于农业生态环境地球化学调查与评价、生物样品测试、农产品质量与食品安全评价样品测试时的分析仪器校正、分析方法评价和分析质量监控等多个领域。  相似文献   

A novel coupled FDM-DEM modelling method for flexible membrane boundary in laboratory tests     

Hua-Xiang Zhu  Zhen-Yu Yin  Qiang Zhang 《国际地质力学数值与分析法杂志》2020,44(3):389-404

Difficulties are involved in discrete element method (DEM) modelling of the flexible boundary, that is, the membranes covering the soil sample, which can be commonly found in contemporary laboratory soil tests. In this paper, a novel method is proposed wherein the finite difference method (FDM) and DEM are coupled to simulate the rubber membrane and soil body, respectively. Numerical plane strain and triaxial tests, served by the flexible membrane, are implemented and analysed later. The effect of the membrane modulus on the measurement accuracy is considered, with analytical formulae derived to judge the significance of this effect. Based on an analysis of stress-strain responses and the grain rotation field, the mechanical performances produced by the flexible and rigid lateral boundaries are compared for the plane strain test. The results show that (1) the effect of the membrane on the test result becomes more significant at larger strain level because the membrane applies additional lateral confining pressure to the soil body; (2) the tested models reproduce typical stress and volumetric paths for specimens with shear bands; (3) for the plane strain test, the rigid lateral boundary derives a much higher peak strength and larger bulk dilatation, but a similar residual strength, compared with the flexible boundary. The latter produces a more uniform (or ‘diffuse') rotation field and more mobilised local kinematics than does the former. All simulations show that the proposed FDM-DEM coupling method is able to simulate laboratory tests with a flexible boundary membrane.  相似文献   

不同结构林带防风效能风洞模拟     

李晓烨  王克俭  谷建才  刘启国  崔严 《中国沙漠》2019,39(6):118-125

防风林带结构是影响防风效能的主要因素。建立不同宽度、不同株行距林带防风效能与林带后距离之间的统计模型，可以为防风林建设提供指导性意见。通过风洞实验，在11 m·s^-1风速下，对4种宽度、5种株行距林带的背风面0~10H（H为林带高度）的风速进行测定，采用曲线参数估计法、傅立叶模型、SSF模型（Sum of Sin Functions），构建了不同结构林带防风效能与林带后距离间的统计模型。结果表明：傅立叶模型拟合不同宽度林带的防风效能与林带后距离的关系效果最优，可决系数（R²）均在98%以上；SSF模型拟合不同株行距林带的防风效能与林带后距离的关系效果最优（R²>0.98）。根据构建的统计模型，风速为11 m·s^-1左右时，林带宽度8 m（两行一带）的防风林的防风效能存在明显优势；5种株行距的林带中，株行距为8 m×8 m的防风林带本试验条件下防风效果最好。  相似文献   

Two-stage permutation tests for determining homogeneity within a spatial cluster     

Qiliang Liu  Wenkai Liu  Min Deng  Yaolin Liu 《International journal of geographical information science》2019,33(9):1718-1738

The discovery of spatial clusters formed by proximal spatial units with similar non-spatial attribute values plays an important role in spatial data analysis. Although several spatial contiguity-constrained clustering methods are currently available, almost all of them discover clusters in a geographical dataset, even though the dataset has no natural clustering structure. Statistically evaluating the significance of the degree of homogeneity within a single spatial cluster is difficult. To overcome this limitation, this study develops a permutation test approach Specifically, the homogeneity of a spatial cluster is measured based on the local variance and cluster member permutation, and two-stage permutation tests are developed to determine the significance of the degree of homogeneity within each spatial cluster. The proposed permutation tests can be integrated into the existing spatial clustering algorithms to detect homogeneous spatial clusters. The proposed tests are compared with four existing tests (i.e., Park’s test, the contiguity-constrained nonparametric analysis of variance (COCOPAN) method, spatial scan statistic, and q-statistic) using two simulated and two meteorological datasets. The comparison shows that the proposed two-stage permutation tests are more effective to identify homogeneous spatial clusters and to determine homogeneous clustering structures in practical applications.  相似文献   

Test and analysis of reinforced concrete (RC) precast shear wall assembled using steel shear key (SSK)     

Shao-Dong Shen  Peng Pan  Qi-Song Miao  Wen-Feng Li  Run-Hua Gong 《地震工程与结构动力学》2019,48(14):1595-1612

Reinforced concrete (RC) precast shear walls are extensively applied in practical engineering, owing to their fast construction speed. However, because of the transport conditions, RC precast shear walls have to be separated into small wall segments during the factory prefabrication procedure before being assembled on site. Typically, wet-type jointing methods are adopted to link the segments, which is time-consuming and results in unreliable post-pouring area strength. To overcome this problem, the novel scheme of the steel shear key (SSK) featuring steel shear panels and combined fillet and plug welding is proposed. Three RC precast shear wall specimens with different linking strength, termed as weakened SSK wall, standard SSK wall, and strengthened SSK wall, respectively, and an integrated shear wall specimen were designed. Quasi-static cyclic loading was applied to investigate the specimens' dynamic properties. The test results suggest the prefabricated wall segments equipped with SSKs showed reliable stiffness and bearing capacity and were improved in energy dissipation ability, compared with conventional shear walls. As the shear stiffness and number of equipped SSKs increased, the specimens exhibited higher strength, but their ductility and energy dissipation were slightly decreased. Most importantly, the standard SSK wall specimen could achieve satisfactory bearing capacity and deformability and is thus recommended for precast building structures. Finite element method (FEM) models were established to validate the test results, and parametric study analysis was conducted based on the coupling ratio of the SSK walls. Finally, an appropriate coupling ratio range is recommended for practical engineering applications.  相似文献